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41.
Experiments concerning the properties of soap films have recently been carried out and these systems have been proposed as experimental versions of theoretical two‐dimensional liquids. A silk filament introduced into a flowing soap film, was seen to demonstrate various stable modes, and these were, namely, a mode in which the filament oscillates and one in which the filament is stationary and aligns with the flow of the liquid. The system could be forced from the oscillatory mode into the non‐ oscillatory mode by varying the length of the filament. In this article we use numerical and computational techniques in order to simulate the strongly coupled behaviour of the filament and the fluid. Preliminary results are presented for the specific case in which the filament is seen to oscillate continuously for the duration of our simulation. We also find that the filament oscillations are strongly suppressed when we reduce the effective length of the filament. We believe that these results are reminiscent of the different oscillatory and non‐oscillatory modes observed in experiment. The numerical solutions show that, in contrast to experiment, vortices are created at the leading edge of the filament and are preferentially grown in the curvature of the filament and are eventually released from the trailing edge of the filament. In a similar manner to oscillating hydrofoils, it seems that the oscillating filaments are in a minimal energy state, extracting sufficient energy from the fluid to oscillate. In comparing numerical and experimental results it is possible that the soap film does have an effect on the fluid flow especially in the boundary layer where surface tension forces are large. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
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We study the synthesis of organic-inorganic hybrids in the molten state of the polymer without solvent, by reactive processing. The synthesis is based in a first step upon the crosslinking of ethylene vinyl acetate copolymer (EVA) through an exchange reaction between the pendant ester groups of EVA and tetrapropoxysilane (TPOS) in presence of dibutyltin oxide (DBTO) as an indispensable catalyst. Then in a second step the hydrolysis-condensation reactions of residual alkoxide groups results in silica network formation, which is covalently bonded with the organic network. An original approach was developed to correlate the evolution of the hydrolysis-condensation reactions through the assessment of propanol by gas chromatography and the evolution of the morphology through SAXS and TEM analysis. Silica-rich domains with a diameter close to 5 nm are obtained.  相似文献   
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This note chronicles various roles played by the Yasuda-Shimada theorem in some recent developments of Riemann--Finsler geometry. We shall demonstrate that the said theorem is, at various stages of its life, an enigma, an inspiration, a flawed icon, and a powerful catalyst.  相似文献   
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The rotational barriers of the CC bonds of halocarbons are believed to be rather different than those of hydrocarbons. We wish to systematically study the effect of halogen substituents on the conformational flexibility of hydrocarbons. As our initial approach to this problem, we have synthesized the following molecules: Pyrene-(CF2)n-Pyrene (n=3, 4, and 6) and Pyrene-(CF2)n-F (n=4 and 6). We describe here the concentration and temperature dependence of the emissive behavior of these materials.  相似文献   
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John Pegg  David Tall 《ZDM》2005,37(6):468-475
In this paper, the development of mathematical concepts over time is considered. Particular reference is given to the shifting of attention from step-by-step procedures that are performed in time, to symbolism that can be manipulated as mental entities on paper and in the mind. The development is analysed using different theoretical perspectives, including the SOLO model and various theories of concept construction to reveal a fundamental cycle underlying the building of concepts that features widely in different ways of thinking that occurs throughout mathematical learning.  相似文献   
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We clarify the way in which cosmological perturbations of quantum origin, produced during inflation, assume classical properties. Two features play an important role in this process: First, the dynamics of fluctuations which are presently on large cosmological scales leads to a very peculiar state (highly squeezed) that is indistinguishable, in a precise sense, from a classical stochastic process. This holds for almost all initial quantum states. Second, the process of decoherence by interaction with the environment distinguishes the field amplitude basis as the robust pointer basis. We discuss in detail the interplay between these features and use simple analogies such as the free quantum particle to illustrate the main conceptual issues.  相似文献   
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